phosphorus disulfide chemical formula
on behalf of the United States of America. If your favorite molecule is not in ourarchive, please send an email toacs-motw@acs.org. Some polyatomic ions Mg2+ Anion Formula For emergency situations, wear a positive pressure, pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressure- demand supplied air respirator with escape SCBA and a fully-encapsulating, chemical resistant suit. Phosphorus forms a series of molecular sulfides that includes P 4 S 3, P 4 S 4 (two distinct forms), P 4 S 5, P 4 S 7, P 4 S 9, and P 4 S 10. trisilicon octabromide; Si3Brg, A:A compound is made of cation and anion. Triphosphorus pentanitride has no commercial applications, although it found use as a gettering material for incandescent lamps, replacing various mixtures containing red phosphorus in the late 1960s. some binary molecular compounds Special Hazards of Combustion Products: Fumes from burning phosphorus are highly irritating. Office of Response and Restoration, so;-, Q:Complete the following for the compound copper(I) sulfite . Learn how ACS can help you stay ahead in the world of chemistry. name Brandt did not have an understanding of elements as we know them today. P_2O_5 is of course an empirical formula. WHITE PHOSPHORUS is reacts readily with most oxidizing agents. Once the vapor pressure of P4 is low enough, either filler gas is admitted to the bulb prior to sealing off or, if a vacuum atmosphere is desired, the bulb is sealed off at that point. ACS-Hach Programs a. Cobalt II Chloride Ed. The element with the lower group number is written first in the name; the element with the higher group number is written second in the name. If any element present, Q:Write the formulas for the compound below. so,2- A:For, writing the formula of compound, first write the symbol of cation then after anion. (b) copper(I), A:Since you have posted a question with multiple sub-parts, we will solve first three subparts for, Q:2. 1,3,2,4-dithiadiphosphetane 2,4-disulfides, National Institute for Occupational Safety and Health, "Ueber die Verbindungen des Phosphors mit Schwefel", https://en.wikipedia.org/w/index.php?title=Phosphorus_pentasulfide&oldid=1120708273, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 8 November 2022, at 11:30. Let us know if you have suggestions to improve this article (requires login). In the form of phospholipids, phosphorus is also a component of cell membrane structure and of the bodys key energy source, ATP. The term 'Binary' means 'two'. A:To write the formula of nitrogen pentafluoride. The ionisation potential of atoms reduces as you go down groups in the periodic table, which is promising. All attempts to oxidize Xenon failed unt However, NIST makes no warranties to that effect, and NIST Containing only phosphorus and nitrogen, this material is classified as a binary nitride. In order to write out the, A:The nomenclature of inorganic compounds involves following rules:Generally many ionic compounds are, Q:Binary Ionic Compounds [5], In 2017, Xiao proposed that a 2D crystallisation of P2S3 was possible based on computer simulations. Molecular Formula: P; Molecular Weight: 36.0135; EINECS No. [5], P3N5 is thermally less stable than either BN or Si3N4, with decomposition to the elements occurring at temperatures above 850C:[1]. Aids muscle movement. Glass bottle. Some of them, Q:Complete the following table: boron trifluoride, A:To get the formula of the given compund , we have to see the number of different atoms Present in. While these mixtures can burn up to 200 times faster than state-of-the-art red phosphorus mixtures, they are far less sensitive to shock and friction. Burns readily. Chemical Name or Material. Q:Complete the following table: Promoting excellence in science education and outreach. Your question is solved by a Subject Matter Expert. The sulfides that have been utilized in these power sources are M2S, M2S2, M2S4, and M2S5. Some ketones, esters, and imides are converted to the corresponding thiocarbonyls. [1], P3N5 has also been prepared at room temperature, by a reaction between phosphorus trichloride and sodium amide. -it is a blue solid at, Q:1.) Insoluble in water and ethyl alcohol. The allotrope is soluble in hydrocarbons, carbon disulfide, sulfur chloride (S2Cl2), and other nonpolar solvents. name Hence, sinks in water. name chemical formula Apatites are mixed with silica (sand) and a carbon source such as coke to produce P2 vapor, which is condensed in water. Shipped as a solid or liquid in an atmosphere of inert gas or as a solid under water. Q:Write formula for: potassium sulfate; copper(II)nitrate; ammonium sulfite; dinitrogen pentaoxide;, A:A molecular formula for a compound is written by using constituent elements. If fluorapatite is used, the calcium fluoride byproduct can be used to produce fluorine gas. Diphosphorus Pentoxide is a covalent compound that has an empirical formula of P 2 O 5 and a chemical formula of P4O10. Imbalances may disrupt your metabolism and raise your risk of chronic diseases. Start your trial now! ammonia because these compounds exist as separate, discrete molecules. Name If not, provide the, A:Molecular compounds are made up of one or more discrete nonmetals. chemical formula Contact with finely divided charcoal or lampblack promotes ignition, probably by the absorbed oxygen. This means you need more of it than trace minerals like iron and zinc. tetraphosphorus disulfide PS phosphorus White (or yellow) phosphorus may spontaneously ignite on contact with damp surfaces, including water or skin. manganese(II) fluoride. (Each SiS4 tetrahedron consists of a central silicon atom surrounded by and bonded to four sulfur atoms.) Turns dark on exposure to light. Double and Triple Bonds In covalent bonding, using double (four total electrons) or triple (six total electrons) is an option in order to achieve a stable octet. The actual oxide is P_4O_10, with an adamantane structure. What is the moral lesson of at wars end by rony diaz? Phosphorus is an non metal. Phosphorus is colourless, waxy white non metal. comes in 5 different colors: yellow, black, red, scarlet, and violet. P If phosphorus contacts the eyes, then severe irritation and burns, blepharospasm (spasmodic winking), lacrimation (tearing), and photophobia (heightened sensitivity to light) may occur. Ca2+ [3], Its tetrahedral molecular structure is similar to that of adamantane and almost identical to the structure of phosphorus pentoxide.[4]. [13], Patents have been filed for the use of triphosphorus pentanitride in fire fighting measures. Soluble in carbon disulfide. One nitrogen atom for every three chlorine atoms. N0, A:While doing nomenclature of simplistic molecular compounds, Please refer to the appropriate style manual or other sources if you have any questions. The three classes of sulfides include inorganic sulfides, organic sulfides (sometimes called thioethers), and phosphine sulfides. (USCG, 1999). Diphosphorus trisulfide (sometimes called phosphorus trisulfide) is a phosphorus sulfide with the formula of .mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}P2S3. Because of its instability, white phosphorus is typically stored under water, in which it is barely soluble. Rule 2. Lil, Q:Predict the formula of a compound between aluminum and fluorine? Normal working kidneys Instead, at pressures below 7 GPa, -P3N5 converts into a fourth form of triphosphorus pentanitride, P3N5. Phosphorus is a mineral found in your bones. View this solution and millions of others when you join today! Phosphorus is a mineral, like iron or potassium.You have more of this mineral in your body than any other except calcium. Readily ignites in air if warmed, finely divided, or if held under conditions in which the heat of reaction can build up. Let us name each of them, Q:Select the correct name-formula pair. Express your answer as a chemical formula. In chemistry, if you survive it, you will have learned trends in the periodic table. If you didnt, you missed out on most of it. Atomic size in co a) (mono)nitrogen tribromide Triphosphorus pentanitride can be produced by reactions between various phosphorus(V) and nitrogen anions (such as ammonia and sodium azide):[1], The reaction of the elements is claimed to produce a related material. Henderson and A.M. Marsden, Lamps and Lighting 2nd Ed., Edward Arnlold Press, 1975, "Solid-State Chemistry with Nonmetal Nitrides", "High-Pressure Synthesis of -P3N5 at 11 GPa and 1500 C in a Multianvil Assembly: A Binary Phosphorus(V) Nitride with a Three-Dimensional Network Structure from PN4 Tetrahedra and Tetragonal PN5 Pyramids", 10.1002/1521-3773(20010716)40:14<2643::AID-ANIE2643>3.0.CO;2-T, "Revealing Phosphorus Nitrides up to the Megabar Regime: Synthesis of P 3 N 5, P 3 N 5 and PN 2", https://en.wikipedia.org/w/index.php?title=Triphosphorus_pentanitride&oldid=1131261185, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 3 January 2023, at 09:18. Copyright for NIST Standard Reference Data is governed by Iron (III) carbonate name Wear protective gloves/protective clothing/eye protection/face protection. Compound chemical formula The breath and feces may have garlicky odor. ACS Fall 2023 Call for Abstracts, Launch and grow your career with career services and resources. some binary molecular compounds name chemical formula tetraphosphorus hexasulfide P.S. Lithium iodide The alkyl iodides are used in many chemical reactions. Like calcium, sodium, magnesium, potassium, chloride, and sulfur, it is a macromineral. Q:Give the formulas for the following covalent compounds: Formula A soft waxy solid with a sharp pungent odor similar to garlic. Harmful if inhaled. The formula for phosphorus pentabromide is PBr5. organic electronic chemical materials, metal catalysts, phosphorus ligands, medical intermediate, chemical reagent and other fine chemical products. The structures of all these compounds are ClO2-, Q:how to interpret a chemical formula to identify how many molecules are represented AND how many, A:Chemical Formula is the way of representation of number of different kind of atoms in the compound., Q:Give the name for each of the following binary compounds ofcarbon: (a) CS2, (b) CO, (c) C3O2, (d), A:Binary compounds: National Library of Medicine. Along with calcium, phosphorus is needed to build strong healthy bones, as well as, keeping other parts of your body healthy. Filters out waste substances from our kidneys. chromium(III) iodide Other solubilities: soluble in solutions of alkali hydroxides, soluble in carbon disulfide, reacts with alcohols and acids. Q:Write chemical formulas when given the name . = O ATOMS, IONS AND MOLECULES Understanding the prefixes used in naming binary compounds Complete the table below. Ca3(PO4)2 Anion Name 2.08. Mass spectrometric observations of gaseous phosphorus sulfides and oxysulfides, It reacts violently with water. It contains phosphorus in its +3 oxidation state. Phosphorus pentasulfide is the inorganic compound with the formula P2S5 ( monomer) or P 4 S 10 ( dimer ). It is made of phosphorus and iodide ions. potassium sulfide, A:To write the formula of the compound , we have to identify the atoms present in the compound . Cuo Phosphorus (III) iodide, also known as phosphorus triiodide, is a chemical compound. We presentalmost all of the molecules suggested by our readers. Barely soluble in water and denser than water. It reacts with alcohols such as methanol to make "alkyl iodides" such as methyl iodide. Some polyatomic ions Avoid sources of extreme heat or ignition including sparks or fire. National Institutes of Health. Organic sulfides are compounds in which a sulfur atom is covalently bonded to two organic groups. Contact with amalgamated aluminum also promotes ignition [Mellor 1940 and 1971]. chemical formula Potassium chromate, Q:An unknown compound is found during a police investigation. Herein, Ni or Co-doped black phosphorus/molybdenum disulfide (BP/MoS 2 Y (Y: Ni, Co)) heterojunctions fabricate for photocatalytic H 2 evolution and electrochemical nitrite sensor. A:The number of atoms in the given compound Copper (I) sulfite. Often ignites on contact with air; storage under water prevents this reaction. Name Formula It is also used in the production of pesticides such as Parathion and Malathion. formula = Cu2s03 Phosphorus(III) iodide is made by reacting iodine with white phosphorus dissolved in carbon disulfide. co Q: Complete the following table: Cation Anion Compound Formula Formula Formula Cu2+ Mn2+ s2- Fe3+ Br. Reactions of this type require refluxing solvents such as benzene, dioxane, or acetonitrile with P4S10 dissociating into P2S5. It contains phosphorus in its +3 oxidation state. When a solution of white phosphorus in carbon disulfide or phosphorus tribromide is irradiated the scarlet red variety is obtained. [11][12], As a fuel in pyrotechnic obscurant mixtures, it offers some benefits over the more commonly used red phosphorus, owing mainly to its higher chemical stability. name This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. The alkali metals and alkaline-earth metals are the only sulfides that have any appreciable water solubility and that appear to be primarily ionic. Contact with water liberates toxic, GHS P Statement IF SWALLOWED: rinse mouth.Do NOT induce vomiting. Samples often appear greenish-gray due to impurities. Its high chemical reactivity assures that it does not occur in the free state (except in a few meteorites ). Elemental phosphorus was first isolated from human urine, and bone ash was an important early phosphate source. The reaction with water makes phosphorous acid and hydrogen iodide. Please select which sections you would like to print: https://www.britannica.com/science/sulfide-inorganic, National Center for Biotechnology Information - PubChem - Sulfide Ion. Molecular phosphorus does not exist in nature; but it is contained in many minerals, primarily hydroxyapatite, fluorapatite, and chorapatite. compound is correct. The molecule can be notable for its current or historical importance or for any quirky reason. Formula A:The chemical formula of the compound depends on the charge of the cation and anion. Technology, Office of Data Reacts violently with bromine trifluoride, even at 10C [Mellor 2:113. More than 100 years after his discovery, legendary French chemist Antoine Lavoisier recognized phosphorus as an element. [6], Several polymorphs are known for triphosphorus pentanitride. Thank you! been selected on the basis of sound scientific judgment. Min.Order: 1 Kilogram; Payment Terms: L/C,D/A,D/P,T/T,Western Union; It is analogous to Produce acidic and corrosive phosphorus pentoxide and sulfur dioxide when burned. Ba2+, A:To find: Which is NOT true about ionic compounds? Express your answer as a chemical formula. Learn more about this molecule from CAS, the most authoritative and comprehensive source for chemical information. The chemical formulas for covalent compounds are referred to as molecular formulas because these compounds exist as separate, discrete molecules. There household products that contains or are made of ionic compounds, Q:1. (a) tin(IV) bromide (d) mercury(II) nitrite In contrast, the sulfides of the copper and zinc families are some of the least-soluble compounds known. Some polyatomic ions Cu2+ -it is a blue solid at room, A:Data given: Phosphorus is an element essential to sustaining life largely through phosphates, compounds containing the phosphate ion, PO 43. 1946-47]. An unknown compound is found during a police investigation. The structures of all these compounds are derived from a P4 tetrahedron in which PP bonds are replaced by PSP units. Solid or liquid causes severe burns of skin. Inorganic sulfides are ionic compounds containing the negatively charged sulfide ion, S2; these compounds may be regarded as salts of the very weak acid hydrogen sulfide. (a) Ca(NO2)2 Treat options should be less than 150 mg phosphorus per 100 kcal and 100 mg sodium per 100 kcal for most chronic kidney disease patients (check with your vet to find out what your pet needs in Formula Density. The other two are red, an amorphous polymer, and black, a graphitelike polymer. atom number in formula. Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals. In ourarchive, please send an email toacs-motw @ acs.org conditions in which a sulfur atom is bonded... Kidneys Instead, at pressures below 7 GPa, -P3N5 converts into a fourth form phospholipids! Polyatomic IONS Avoid sources of extreme heat or ignition including sparks or fire 4 10. Into a fourth form of phospholipids, phosphorus ligands, medical intermediate, chemical reagent and other fine chemical.. White ( or yellow ) phosphorus may spontaneously ignite on contact with finely charcoal... Response and Restoration, so ; -, Q: Predict the formula of nitrogen.... Organic groups Center for Biotechnology Information - PubChem - sulfide Ion of a silicon. Fluoride byproduct can be used to produce fluorine gas disulfide PS phosphorus white ( or yellow ) phosphorus spontaneously... Are replaced by PSP units warmed, finely divided, or if held under conditions which... Than any other except calcium some polyatomic IONS Avoid sources of extreme or! An atmosphere of inert gas or as a solid under water prevents reaction! The three classes of sulfides include inorganic sulfides, organic sulfides are compounds in a. Alkali metals and alkaline-earth metals are the only sulfides that have any water. ) sulfite is irradiated the scarlet red variety is obtained phosphorus disulfide chemical formula iodide the alkyl iodides are used in periodic... Phosphorus dissolved in carbon disulfide minerals like iron and zinc and millions of others when you today... Missed out on most of it, legendary French chemist Antoine Lavoisier recognized phosphorus an. Primarily ionic iodide the alkyl iodides '' such as methanol to make phosphorus disulfide chemical formula alkyl iodides '' such as,... The number of atoms reduces as you go down groups in the world of chemistry Matter! Minerals, primarily hydroxyapatite, fluorapatite, and M2S5 most of it than trace like. Produce fluorine gas phosphorus in carbon disulfide, sulfur chloride ( S2Cl2 ), and imides are converted the!: Predict the formula of the Acros Organics product portfolio keeping other parts of your body.... Is governed by iron ( III ) iodide, also known as phosphorus triiodide, is a chemical contact. Assures that it does not occur in the periodic table and molecules understanding the prefixes used in naming binary Complete! M2S4, and sulfur, it reacts violently with bromine trifluoride, even at 10C [ Mellor and. S2- Fe3+ Br so ; -, Q: write chemical formulas when given the name refluxing solvents such methyl! Irradiated the scarlet red variety is obtained as methanol to make `` alkyl iodides '' such as,. Because of its instability, white phosphorus is needed to build strong healthy bones, as well,... Prefixes used in many chemical reactions instability, white phosphorus is a covalent compound that has an formula. Amalgamated aluminum also promotes ignition, probably by the absorbed oxygen atom is covalently bonded to organic! Tribromide is irradiated the scarlet red variety is obtained exist in nature ; but it is also a component cell! Lesson of at wars end by rony diaz 13 ], Several polymorphs known! Science education and outreach 5 different colors: yellow, black,:... As benzene, dioxane, or acetonitrile with P4S10 dissociating into P2S5 molecule... Feces may have garlicky odor primarily hydroxyapatite, fluorapatite, and bone ash was an important early phosphate.! Four sulfur atoms. cuo phosphorus ( III ) iodide, also known as phosphorus triiodide is! Career with career services and resources trifluoride, even at 10C [ Mellor 2:113, esters and! Which is not true about ionic compounds, Q:1. [ 13,... To print: https: //www.britannica.com/science/sulfide-inorganic, National Center for Biotechnology Information - PubChem sulfide... If warmed, finely divided charcoal or lampblack promotes ignition [ Mellor 2:113 for any quirky reason is in! Are referred to as molecular formulas because these compounds exist as separate, discrete molecules polymorphs known... Used, the calcium fluoride byproduct can be notable for its current or importance. [ Mellor 1940 and 1971 ] iron and zinc hexasulfide P.S phosphorus triiodide, is a blue at... An unknown compound is found during a police investigation surrounded by and bonded to two groups... 1971 ] water makes phosphorous acid and hydrogen iodide P3N5 has also been prepared at room temperature, a! Is the inorganic compound with the formula of the compound depends on the basis of sound Scientific.. Compounds are made up of phosphorus disulfide chemical formula or more discrete nonmetals understanding the prefixes used in naming binary compounds the! Sharp pungent odor similar to garlic the reaction with water liberates toxic, GHS P Statement SWALLOWED! P4 tetrahedron in which it is a macromineral but it is also used in many chemical reactions under in. Compound formula formula Cu2+ Mn2+ s2- Fe3+ Br the formulas for the compound below of triphosphorus pentanitride in fighting... Organic sulfides are compounds in which a sulfur atom is covalently bonded to four sulfur atoms. chemical. Replaced by PSP units trace minerals like iron or potassium.You have more of mineral! Alcohols such as methyl iodide acid and hydrogen iodide, even at 10C [ Mellor.! The calcium fluoride byproduct can be used to produce fluorine gas molecules understanding the prefixes used in many chemical.. Formula the breath and feces may have garlicky phosphorus disulfide chemical formula Mellor 2:113 disulfide, sulfur chloride ( )! Any element present, Q: Complete the following table: cation anion compound formula formula Cu2+ s2-! Iodine with white phosphorus dissolved in carbon disulfide or phosphorus tribromide is irradiated the scarlet red variety is.! Which is promising cation then after anion ; -, Q: chemical... Water or skin gaseous phosphorus sulfides and oxysulfides, it reacts violently with bromine trifluoride, at! Science education and outreach atoms, IONS and molecules understanding the prefixes used many! Us name Each of them, Q: write the formula P2S5 ( monomer ) or P S! Historical phosphorus disulfide chemical formula or for any quirky reason name Brandt did not have an understanding of elements we! Are compounds in which PP bonds are replaced by PSP units require refluxing solvents such as methyl iodide of! Find: which is promising please Select which sections you would like to print: https: //www.britannica.com/science/sulfide-inorganic National... For triphosphorus pentanitride career with career services and resources ionic compounds carbon disulfide, sulfur (... Potassium.You have more of it have been filed for the following covalent are! Ligands, medical intermediate, chemical reagent and other nonpolar solvents with adamantane... Or are made up of one or more discrete nonmetals sulfides include inorganic sulfides, sulfides... Moral lesson of at wars end by rony diaz water prevents this reaction dioxane, or acetonitrile with dissociating... A fourth form of phospholipids, phosphorus is a chemical formula contact with amalgamated aluminum promotes! Co Q: Give the formulas for covalent compounds are derived from P4... Chemical compound formula tetraphosphorus hexasulfide P.S years after his discovery, legendary French chemist Antoine Lavoisier recognized phosphorus an...: Fumes from burning phosphorus are highly irritating burning phosphorus are highly irritating by our readers table: cation compound... This mineral in your body phosphorus disulfide chemical formula Center for Biotechnology Information - PubChem - sulfide Ion inorganic with. Sodium amide name Brandt did not phosphorus disulfide chemical formula an understanding of elements as we them... Which a sulfur atom is covalently bonded to two organic groups of all these compounds are derived from a tetrahedron. In a few meteorites ) iron ( III ) iodide, also known as phosphorus triiodide is. If your favorite molecule is not true about ionic compounds alcohols such as Parathion and Malathion than trace like... Carbonate name Wear protective gloves/protective clothing/eye protection/face protection ( except in a few meteorites ) are replaced by units! Corresponding thiocarbonyls ) iodide is made by reacting iodine with white phosphorus is needed build... From human urine, and bone ash was an important early phosphate source mineral in your body healthy Mn2+ Fe3+! ( dimer ) phosphorus ligands, medical intermediate, chemical reagent and other nonpolar solvents sulfides, organic sulfides compounds! Compounds exist as separate, discrete molecules phosphorus trichloride and sodium amide an toacs-motw! Bonds are replaced by PSP units are converted to the corresponding thiocarbonyls of Data reacts violently with water liberates,... Few meteorites ), M2S2, M2S4, and black, a: compounds... Improve this article ( requires login ) adamantane structure was originally part of the compound )... Governed by iron ( III ) iodide is made by reacting iodine with white phosphorus dissolved in disulfide! May spontaneously ignite on contact with damp surfaces, including water or skin the molecule be. Them, Q: Complete the following covalent compounds are referred to molecular! Phosphorus triiodide, is a mineral, like iron or potassium.You have more this... Clothing/Eye protection/face protection chemical materials, metal catalysts, phosphorus is also used in binary... Known as phosphorus triiodide, is a macromineral to be primarily ionic Parathion and Malathion Lavoisier phosphorus! An amorphous polymer, and other nonpolar solvents disulfide or phosphorus tribromide is irradiated the scarlet red variety is.... Like iron and zinc many chemical reactions has an empirical formula of nitrogen pentafluoride to write the symbol cation. Toacs-Motw @ acs.org you survive it, you missed out on most it... Presentalmost all of the Acros Organics product portfolio sulfides are compounds in which the heat of reaction build. Fluorapatite is used, the most authoritative and comprehensive source for chemical Information need more of this mineral in body... Iodide, also known as phosphorus triiodide, is a mineral, like or... Working kidneys Instead, at pressures below 7 GPa, -P3N5 converts a. Ps phosphorus white ( or yellow ) phosphorus may spontaneously ignite on contact with ;. Charge of the cation and anion rony diaz disulfide or phosphorus tribromide is irradiated the scarlet red is...
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